Effect of CuO Nanoparticle Size and Concentration on Thermal Enhancement in Shell-and-Tube Heat Exchangers

Keywords: CuO nanoparticles, Heat transfer, Nanofluid, Shell and tube heat exchanger, Simulation

Abstract

In this study, a custom-designed shell-and-tube heat exchanger (STHE) system was developed and initially modeled via simulation under nanoparticle-free conditions to establish baseline heat transfer parameters. Flow regimes were identified through Reynolds number calculations at different flow rates, and the corresponding convective heat transfer coefficients (hi, ho), overall heat transfer coefficient (U), and heat duty (Q) values were determined. Following simulation calibration, experimental investigations were conducted using CuO–water nanofluids with two distinct particle sizes (38 nm and 20 µm) and three concentrations (0.25%, 0.5%, and 0.75%). The impact of these parameters on the thermal performance of the STHE was evaluated under varying inlet temperature conditions. Experimental results revealed that cold fluid outlet temperatures increased significantly with the addition of nanoparticles, while hot fluid outlet temperatures decreased, indicating enhanced heat absorption. For 38 nm particles, the cold-side enhancement (ΔT) ranged from 1.0 °C to 2.2 °C, corresponding to approximately 5–12% improvement relative to the baseline. In contrast, 20 µm particles exhibited ΔT values of 1.5–2.7 °C, equating to a 6–14% increase depending on concentration and inlet temperature. The most pronounced enhancements were observed at 0.5% and 0.75% concentrations, particularly at higher temperature gradients, demonstrating that both particle size and concentration play critical roles in nanofluid-mediated heat transfer enhancement.

Author Biographies

Gurkan Akarken, Canakkale Onsekiz Mart University

Energy Resources Application and Research Center

Canakkale, Turkey

Ugur Cengiz, Canakkale Onsekiz Mart University

Chemical Engineering

Canakkale, Turkey

Tijen Ennil Bektas, Canakkale Onsekiz Mart University

Chemical Engineering

Canakkale, Turkey

References

Aras, O., & Bayramoğlu, M. (2012). A MINLP study on shell and tube heat exchanger: Hybrid branch and bound/meta-heuristics approaches. Industrial & Engineering Chemistry Research, 51(43), 14158–14170. https://doi.org/10.1021/ie3011462

Fang, B., Tan, Y., Li, C., Cao, Y., Liu, J., Schweizer, P. J., Shi, H., Zhou, B., Chen, H., & Hu, Z. (2016). Energy sustainability under the framework of telecoupling. Energy, 106, 253–259. https://doi.org/10.1016/j.energy.2016.03.055

Chen, P., Wu, Y., Meng, J., He, P., Li, D., Coffman, D. M., & Guan, D. (2022). The heterogeneous role of energy policies in the energy transition of Asia–Pacific emerging economies. Nature Energy, 7(7), 588–596. https://doi.org/10.1038/s41560-022-01029-2

Rostami, S., Nadooshan, A. A., Raisi, A., & Bayareh, M. (2021). Modeling the thermal conductivity ratio of an antifreeze-based hybrid nanofluid containing graphene oxide and copper oxide for use in thermal systems. Journal of Materials Research and Technology, 11, 2294–2304. https://doi.org/10.1016/j.jmrt.2021.02.044

Hu, X. L., Zhang, T., Chen, J., Gao, H., & Cai, W. (2016). Novel synthesis of CuO nanofiber balls and films and their UV–visible light filtration property. Ceramics International, 42(7), 8505–8512. https://doi.org/10.1016/j.ceramint.2016.02.076

Sözen, A., Variyenli, H. I., Özdemir, M. B., Guru, M., & Aytac, I. (2016). Heat transfer enhancement using alumina and fly ash nanofluids in parallel and cross-flow concentric tube heat exchangers. Journal of the Energy Institute, 89(3), 414–424. https://doi.org/10.1016/j.joei.2015.02.012

Feng, L., Wang, R., Zhang, Y., Ji, S., Chuan, Y., Zhang, W., Liu, B., Yuan, C., & Du, C. (2019). In situ XRD observation of CuO anode phase conversion in lithium-ion batteries. Journal of Materials Science, 54(2), 1520–1528. https://doi.org/10.1007/s10853-018-2885-0

Aytac, I. (2021). Investigation of the effect of CuO/water and ZnO/water nanofluids on heat pipe performance. Journal of Polytechnic, 24(3), 963–971. https://doi.org/10.2339/politeknik.755358

Kulkarni, D. P., Das, D. K., & Vajjha, R. S. (2009). Application of nanofluids in heating buildings and reducing pollution. Applied Energy, 86(12), 2566–2573. https://doi.org/10.1016/j.apenergy.2009.03.021

Afsharpanah, F., Mousavi Ajarostaghi, S. S., Hamedani, F. A., & Pour, M. S. (2022). Compound heat transfer augmentation of a shell-and-coil ice storage unit with metal-oxide nano additives and connecting plates. Nanomaterials, 12(6), 1027. https://doi.org/10.3390/nano12061010

Basnet, P., & Chatterjee, S. (2020). Structure-directing property and growth mechanism induced by capping agents in nanostructured ZnO during hydrothermal synthesis—A systematic review. Nano-Structures & Nano-Objects, 22, 100426. https://doi.org/10.1016/j.nanoso.2020.100426

Gan, Y. X., Jayatissa, A. H., Yu, Z., Chen, X., & Li, M. (2020). Hydrothermal synthesis of nanomaterials. Journal of Nanomaterials, 2020, Article 8917013. https://doi.org/10.1155/2020/8917013

Shi, W. D., Song, S. Y., & Zhang, H. J. (2013). Hydrothermal synthetic strategies of inorganic semiconducting nanostructures. Chemical Society Reviews, 42(13), 5714–5743. https://doi.org/10.1039/C3CS60070F

Yang, Q., Lu, Z., Liu, J., Lei, X., Chang, Z., Luo, L., & Sun, X. (2013). Metal oxide and hydroxide nanoarrays: Hydrothermal synthesis and applications as supercapacitors and nanocatalysts. Progress in Natural Science: Materials International, 23(4), 351–366. https://doi.org/10.1016/j.pnsc.2013.06.015

Qi, C., Luo, T., Liu, M., Fan, F., & Yan, Y. (2019). Experimental study on the flow and heat transfer characteristics of nanofluids in double-tube heat exchangers based on thermal efficiency assessment. Energy Conversion and Management, 197, 111877. https://doi.org/10.1016/j.enconman.2019.111877

Zolghadri, A., Maddah, H., Ahmadi, M. H., & Sharifpur, M. (2021). Predicting parameters of heat transfer in a shell and tube heat exchanger using aluminum oxide nanofluid with artificial neural network and self-organizing map. Sustainability, 13(16), 9147. https://doi.org/10.3390/su13168824

Colak, A. B., Akgul, D., Mercan, H., Dalkilic, A. S., & Wongwises, S. (2023). Estimation of heat transfer parameters of shell and helically coiled tube heat exchangers by machine learning. Case Studies in Thermal Engineering, 42, 102734. https://doi.org/10.1016/j.csite.2023.102713

Abdelmagied, M. (2025). Numerical analysis on heat transfer enhancement of Al₂O₃ and CuO–water nanofluids in annular curved tubes. International Journal of Air-Conditioning and Refrigeration, 33(1), 1–10. https://doi.org/10.1007/s44189-024-00066-8

Huseen, H., Jurmut, H. A., & Nasir, K. F. (2025). An experimental study on the effect of nanomaterials, hybrid nanomaterials, and composite nanomaterials on heat exchangers. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 128(2), 33–50. https://doi.org/10.37934/arfmts.128.2.3350

Norouzi, M., Rashidi, F., Noorollahi, Y., & Qom, H. F. (2023). CuO/water and Al₂O₃/water nanofluids as working fluid in an abandoned oil well to improve thermal performance in the seawater desalination process. Journal of the Taiwan Institute of Chemical Engineers, 144, 104754. https://doi.org/10.1016/j.jtice.2023.104754

Parveez, M., & Hanief, M. (2022). Enhancement of heat transfer in helical coil heat exchangers using nanofluids. Chemical and Process Engineering, 43(2), 279–283.

Naseema, Nawazish Mehdi, S., Manzoor Hussain, M., Bashad, S. K., & Samade, M. A. (2018). Heat enhancement of heat exchanger using aluminium oxide and copper oxide nanofluids with different concentrations. Materials Today: Proceedings, 5(2), 6481–6488. https://doi.org/10.1016/j.matpr.2017.12.261

Belaghit, M., & Saim, R. (2024). Enhancing geothermal wellbore heat exchanger performance through rectangular protrusion integration in repurposed abandoned oil wells. International Journal of Heat and Technology, 42(1), 201–209. https://doi.org/10.18280/ijht.420121

Esfe, M. H., & Togharie, D. (2024). Experimental, price-performance and artificial neural network analysis of MWCNT–CuO/water–EG (50–50) nanofluid as a coolant/antifreeze working fluid. Korean Journal of Chemical Engineering, 41(6), 1679–1689. https://doi.org/10.1007/s11814-024-00173-7

Akarken, G., Cengiz, U., & Bektaş, T. E. (2024). Hydrothermal synthesis of CuO nanoparticles: Tailoring morphology and particle size variations for enhanced properties. Journal of Advanced Research in Natural and Applied Sciences, 10(2), 329–336. https://doi.org/10.28979/jarnas.1405595

Phiwdang, K., Suphankij, S., Mekprasart, W., & Pecharapa, W. (2013). Synthesis of CuO nanoparticles by precipitation method using different precursors. In Proceedings of the 10th Eco-Energy and Materials Science and Engineering Symposium (pp. 740–745). https://doi.org/10.1016/j.egypro.2013.06.80827.

Verma, N., & Kumar, N. (2019). Synthesis and biomedical applications of copper oxide nanoparticles: An expanding horizon. ACS Biomaterials Science & Engineering, 5(3), 1170–1188. https://doi.org/10.1021/acsbiomaterials.8b01092

Kayani, Z. N., Umer, M., Riaz, S., & Naseem, S. (2015). Characterization of copper oxide nanoparticles fabricated by the sol–gel method. Journal of Electronic Materials, 44(10), 3704–3709. https://doi.org/10.1007/s11664-015-3867-5

Published
2026-06-30
How to Cite
Akarken, G., Cengiz, U., & Bektas, T. E. (2026). Effect of CuO Nanoparticle Size and Concentration on Thermal Enhancement in Shell-and-Tube Heat Exchangers. Journal of Engineering Research and Applied Science, 15(1), 77-87. Retrieved from https://www.journaleras.com/index.php/jeras/article/view/435
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Articles